Tippy-Toe - Squirrel friend for many years. They first met avenging the death of Monkey Joe (another squirrel). Since then, they've been loyal partners for years.
Nancy Whitehead - roommate and bestie. Just the best
Tomas Lara-Perez/Chipmunk Hunk - Her college crush, which kinda died out. Now they fight crime together
Ken Shiga/Koi Boi - Another animal-themed hero. Cool guy, supremely focused on efficiency
Allene Green - Clone from an Iron Man experiment gone wrong. They basically consider themselves twin sisters and are very devoted to each other, even after Allene was a huge jerk and almost killed her
Werner Schmidt/Brain Drain - Former robot HYDRA man, now a nihilistic hero pal
Iron Man/Tony Stark - Her hero and idol. When she was a teen, at least. Now she realizes he's kind of a mess and is very scientifically responsible. But they're good friends, even if they insult each other on twitter constantly
Spider-Man - Let's be real. Kind of a jerk. But they'll team-up if needed, even if Spidey doesn't take her seriously.
Captain(s) America - They're Captain America! They can't go wrong!
Hulk - Way deeper than anyone gives him credit for. Dude just wants people to be polite!
Thor and Lady Thor - They teamed up once. It was cool.
Luke Cage - Hero for Hire. Father of Dannielle Cage and a cool guy that's doing what he can to support his family
Jessica Jones - Danielle's mother. Incredible, full of amazing personal strength. Doreen privately credits Jessica for inspiring Doreen to truly become a selfless hero.
Danielle Cage - Baby daughter of Luke and Jessica. Doreen was her nanny for a while. Initially using Dani as a means to get into the Avengers, she grew to care for her and risked her life during a HYDRA attack to save her.
Wolverine (Logan) - He stole a taxi from her. They haven't gotten along since.
Mockingbird - Great hero. Nearly died that one time.
Daredevil - Saved her from HYDRA. Had a crush on him. It was awkward for everyone and she tries not to think about it.
The Thing - Member of Fantastic Four. Cool guy!
Iron Fist - some kinda.... ninja man? Seems neat. Close friends with Luke Cage.
The second team Squirrel Girl was recruited to and currently operates on.
Roberto da Costa/Sunspot - Member of New Mutants, bought out AIM and used it to make a superhero team. Running a former terrorist group doesn't help his reputation, but he's a good boss.
Wiccan and Hulking - A great couple. Only two people who didn't join da Costa's dumb plan to invade SHIELD. Trusts them implicitly and anything they might do.
Pod/Enigma - Woman (Enigma) in a relationship with a robot lady (Pod). Things went downhill when Pod died, but Enigma is still very nice.
Hawkeye - Avenger, hero. Didn't trust him for a while but he earned his way into her good book.
Songbird - boy she's sick of double/triple agents. Probably good now?
Toni Ho/Iron Patriot - daughter of that dude that helped Tony build Iron Man. So cool
Red Hulk - that's one heck of a mustache mate
Captain America/Dani Cage - A Captain America from the future and that kid Doreen babysat. "She said I was her favorite nanny!"
Sam Guthrie/Cannonball - Had a huge crush on him and stalked him obsessively. She sent fanmail that was monitored by the FBI. But (apparently???) he was into that and they dated. Then he went edgy for a bit and she dumped him.
Ratatoskr - brainwashed people. Super rude! Beat him
Loki - he's cool now!
Mole Man - tried to seduce Doreen. Extremely uncomfortable around him
Melissa Morbeck - Professor. Doreen trusted and looked up to her. But Morbeck was trying to isolate and frame Doreen for her own crimes. So, not very cool
Close Friends
Nancy Whitehead - roommate and bestie. Just the best
Tomas Lara-Perez/Chipmunk Hunk - Her college crush, which kinda died out. Now they fight crime together
Ken Shiga/Koi Boi - Another animal-themed hero. Cool guy, supremely focused on efficiency
Allene Green - Clone from an Iron Man experiment gone wrong. They basically consider themselves twin sisters and are very devoted to each other, even after Allene was a huge jerk and almost killed her
Werner Schmidt/Brain Drain - Former robot HYDRA man, now a nihilistic hero pal
Superhero Teams
Great Lake Avengers
Mr. Immortal - Leader of the GLA. Kind of a mess, but he gave her the first job she's ever had
Dr. Val/Flatman - no, he's not Mr. Fantastic. But he's doing his best.
Ashley Crawford/Big Bertha - swimsuit model who can superbulk her body. Is constantly disrespected and Doreen will hear no insults against her.
Dinah Soar - killed before Doreen joined, nothing but respect for her
Avengers
Spider-Man - Let's be real. Kind of a jerk. But they'll team-up if needed, even if Spidey doesn't take her seriously.
Captain(s) America - They're Captain America! They can't go wrong!
Hulk - Way deeper than anyone gives him credit for. Dude just wants people to be polite!
Thor and Lady Thor - They teamed up once. It was cool.
The Defenders/2010 New Avengers
Jessica Jones - Danielle's mother. Incredible, full of amazing personal strength. Doreen privately credits Jessica for inspiring Doreen to truly become a selfless hero.
Danielle Cage - Baby daughter of Luke and Jessica. Doreen was her nanny for a while. Initially using Dani as a means to get into the Avengers, she grew to care for her and risked her life during a HYDRA attack to save her.
Wolverine (Logan) - He stole a taxi from her. They haven't gotten along since.
Mockingbird - Great hero. Nearly died that one time.
Daredevil - Saved her from HYDRA. Had a crush on him. It was awkward for everyone and she tries not to think about it.
The Thing - Member of Fantastic Four. Cool guy!
Iron Fist - some kinda.... ninja man? Seems neat. Close friends with Luke Cage.
Doctor Strange - Magic's neat!
2015 New Avengers/USAvengers
Roberto da Costa/Sunspot - Member of New Mutants, bought out AIM and used it to make a superhero team. Running a former terrorist group doesn't help his reputation, but he's a good boss.
Wiccan and Hulking - A great couple. Only two people who didn't join da Costa's dumb plan to invade SHIELD. Trusts them implicitly and anything they might do.
Pod/Enigma - Woman (Enigma) in a relationship with a robot lady (Pod). Things went downhill when Pod died, but Enigma is still very nice.
Hawkeye - Avenger, hero. Didn't trust him for a while but he earned his way into her good book.
Songbird - boy she's sick of double/triple agents. Probably good now?
Toni Ho/Iron Patriot - daughter of that dude that helped Tony build Iron Man. So cool
Red Hulk - that's one heck of a mustache mate
Captain America/Dani Cage - A Captain America from the future and that kid Doreen babysat. "She said I was her favorite nanny!"
Various Heroes/Coffee buddies
Valkyrie - Asgardian. Head of a group of lady fighters.
America Chavez - She's cool! Doreen's not... really sure where she came from, but she seems to be extremely strong?
Kate Bishop - Another Hawkeye.
Monica Rambeau - Doreen didn't believe her about Beyond Corp. Whoops!
Patsy Walker/Hellcat - child star turned superhero
Mutants
X-Men
Kitty Pryde - She was super jealous of her as a kid
Laura/All-New Wolverine - Clone of Logan. She's cool! Doreen helped her work through some stuff and aid a squirrel family
Gabby - Clone of Laura. Doreen bought her a Wolverine. She's cool.
The Rest - Largely aware of most X-Men.
New Mutants
Sam Guthrie/Cannonball - Had a huge crush on him and stalked him obsessively. She sent fanmail that was monitored by the FBI. But (apparently???) he was into that and they dated. Then he went edgy for a bit and she dumped him.
The rest- also cool, knows the basics
Villains
Thanos - beat him
Fin Fang Foom - beat him
Kraven the Hunter - he's cool now!
Galactus - sent to a planet full of nuts
Ratatoskr - brainwashed people. Super rude! Beat him
Loki - he's cool now!
Mole Man - tried to seduce Doreen. Extremely uncomfortable around him
Melissa Morbeck - Professor. Doreen trusted and looked up to her. But Morbeck was trying to isolate and frame Doreen for her own crimes. So, not very cool
Ultron - kinda feels bad for him